scienceneutral
Single‑Atom Strategy Keeps Nickel Active in Sulfur‑Rich Methane Production
Friday, July 3, 2026
Nickel is a stellar catalyst for converting carbon monoxide and dioxide into methane, but it has a fatal flaw: it grabs sulfur so tightly that the catalyst gets poisoned.
Scientists have solved this by introducing single ruthenium atoms into the nickel lattice, effectively creating a decoy that protects the active sites.
- How it works
- Ruthenium atoms attract sulfur because they pull a bit more electron density.
- Once sulfur binds to ruthenium, the strong interaction prevents it from dissociating into reactive fragments that would poison nickel.
- This keeps nearby nickel sites clean and fully active for methane production.
- Performance
- The new alloy tolerates up to 10 parts per million (ppm) of hydrogen sulfide without losing activity.
Plain nickel, in contrast, shuts down quickly under the same conditions.
Broader impact
The strategy of spatially separating sulfur‑binding sites from catalytic ones could safeguard a wide range of metal catalysts against sulfur poisoning.
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